I already proved this, but I think I can reduce my solution.
My solution : There are 4 Sylow 3-subgroup of $S_4$, and denote the set of Syl 3-subgroups by $P=\{P_1,P_2,P_3,P_4\}$.
Then, by a group action $\operatorname{Aut}(S_4) \times P \to P$ defined by $(f,P_i) \to f(P_i)$, obtain a homomorphism $\phi:\operatorname{Aut}(S_4)\to S_4(=\operatorname{Perm}(P))$.
To show that $\ker(\phi)=0$, I suppose $f \in \operatorname{Aut}(S_4)$ fix every Sylow 3-subgroup.
Then I can derive that $f$ fixes every 3-cycle rather easily.
But proving that $f$ fixes $2$-cycle is very long and not seems good, and my question arises here. (I consider every case that $f(ab)$ can be)
Does anyone have a smart idea for proving $f$ fixes 2-cycle?