Here is a more formal proof that complements the other answers.
We want to solve the following feasibility problem
$$
\begin{aligned}
\textrm{find} \quad & X \\
\textrm{s.t.} \quad & X \succ 0 \\
\quad & A^T X + XA \prec 0
\end{aligned} \tag{1}
$$
by solving the following feasibility problem instead
$$
\begin{aligned}
\textrm{find} \quad & X \\
\textrm{s.t.} \quad & X \succeq I \\
\quad & A^T X + XA \preceq -I
\end{aligned} \tag{2}
$$
There are two possible outcomes of the problem in $(2)$: Either an $X$ exists that satisfies the feasibility constraints, or it doesn't. When an $X$ exists that satisfies the feasibility constraints in $(2)$, we want to be able to say that this same $X$ also satisfies the feasibility constraints in $(1)$. Similarly, when an $X$ that satisfies the feasibility constraints in $(2)$ does not exist, then we want to be able to say that there also does not exist an $X$ that satisfies the feasibility constraints in $(1)$.
Therefore, we want to prove the following two statements:
- If there exists an $X$ such that $X \succeq I$ and $A^T X + XA \preceq -I$, then $X \succ 0$ and $A^T X + XA \prec 0$.
- If there does not exist a $Y$ such that $Y \succeq I$ and $A^T Y + YA \preceq -I$, then there does not exist an $X$ such that $X \succ 0$ and $A^T X + XA \prec 0$.
We first prove statement (1) as follows. Suppose that there exists an $X$ such that $X \succeq I$ and $A^T X + XA \preceq -I$. Because $X \succeq I$ and $I \succ 0$, then $X \succ 0$. Similarly, because $A^TX + XA \preceq -I$ and $-I \prec 0$, then $A^TX + XA \prec 0$, as desired. Note that we did not need to use the fact that $F(X) = A^TX + XA$ is homogeneous in $X$ here.
Next, we prove statement (2). We do so by proving the contrapositive of statement (2), which is: "If there exists an $X$ such that $X \succ 0$ and $A^TX + XA \prec 0$. then there exists a $Y$ such that $Y \succeq I$ and $A^TY + YA \preceq -I$". Suppose that there exists an $X$ such that $X \succ 0$ and $A^TX + XA \prec 0$. For any $X \succ 0$, there exists a $\lambda_1 \in (0,\lambda_\min(X)]$ such that $X - \lambda_1 I \succeq 0$, or $X \succeq \lambda_1 I$, where $\lambda_\min(X)$ is the smallest positive eigenvalue of $X$. Similarly, because $A^TX + XA \prec 0$, then there exists a $\lambda_2 \in (0,|\lambda_\max(A^TX + XA)|]$ such that $A^TX + XA + \lambda_2I \preceq 0$, or $A^TX + XA \preceq -\lambda_2I$, where $\lambda_\max(A^TX + XA)$ is the largest negative eigenvalue of $A^TX + XA$.
So, as a first step, choose $\lambda_1$ and $\lambda_2$ such that $\lambda_1 \leq \lambda_2$. This choice is guaranteed to exist, since when $\lambda_\min(X) > |\lambda_\max(A^TX + XA)|$, such that $\lambda_1 \in (0,\lambda_\min(X)]$ and $\lambda_2 \in (0,|\lambda_\max(A^TX + XA)|]$, we can choose $\lambda_1 \in (0,|\lambda_\max(A^TX + XA)| - \varepsilon]$ for a small enough $\varepsilon > 0$, and then choose $\lambda_2 \geq \lambda_1$. All other cases follow similarly.
Next, let $Y = \frac{1}{\lambda_1}X$. Since $X \succeq \lambda_1 I$ as shown above, then $Y \succeq I$, as desired. Similarly, since $A^TX + XA \preceq -\lambda_2I$, then we can multiply both sides of this inequality by $\frac{1}{\lambda_1}$ to get
$$
\begin{align}
\frac{1}{\lambda_1} \cdot \left(A^TX + XA\right) &\preceq -\frac{\lambda_2}{\lambda_1}I \\
A^T \left(\frac{1}{\lambda_1}X\right) + \left(\frac{1}{\lambda_1}X\right) A &\preceq -\frac{\lambda_2}{\lambda_1}I \\
A^T Y + Y A &\preceq -\frac{\lambda_2}{\lambda_1}I
\end{align}
$$
Because $\lambda_1 \leq \lambda_2$, then $-\frac{\lambda_2}{\lambda_1}I \preceq -I$, and so $A^T Y + YA \preceq -I$, as desired. Note that we used the fact that $F(X) = A^TX + XA$ is homogeneous in $X$ here.