It was some time since I've been doing some basic differential geometry, and when I was recently revisiting it I was confused about the following: a unit cube surface $C$ in the ambient space $\Bbb R^3$ is not smooth in a sense that you can't put a tangen plane at its vertices, contrary to the unit sphere $S$ where each point allows for such a surface.
Now, both $C$ and $S$ inherit topology as subspaces of the ambient space, and this topology is the same, they are homeomorphic. I am not sure however whether we can push on them any smooth structure from the ambient space. My point is: is there a way to say that the smooth structure imposed on $C$ truly makes it $C$, and not just a smooth structure from $S$ push onto it?
Maybe it is only possible when there's some extra structure imposed on these spaces, like the Riemann metric. Overall it kinda boils down to the question: is there an intrinsic characterization of the $C$ as a smooth manifold which distinguishes it from $S$?
I have now added clarification that I wonder about intrinsic differences between $S$ and $C$ as smooth manifolds. As topological manifolds they are obviously the same (as stated in the OP), and as Riemann manifolds $C$ and $S$ will be different, but so will be $S$ and an ellipsoid, so nothing that will be caused by the "corners".