The rules of sigfigs say that when adding/subtracting, the sum/difference is rounded to the least precise measurement.
$$32.56 + 2.0592 = 34.6192$$ Rounded answer: $34.62$
The rules also say that when multiplying/dividing, the product/quotient is rounded to the lowest number of sigfigs.
$$25.694 \times 1.85 = 47.5339$$ Rounded answer: $47.5$
What seems a little confusing to me is how one rule might relate to the other in a way that is consistent with the relationship between addition and multiplication.
Take the following expression: $$16.09 \times 5$$
As the definition of multiplication (by natural numbers; the rest are logical extensions of that) as an operation is based on repeated addition, the expression mentioned is equivalent to $16.09 + 16.09 + 16.09 + 16.09 + 16.09$. Since all of these numbers share the same precision, the sum will share that precision: $80.45$.
On the other hand, the sigfig multiplication rule would have me round to one sigfig, $80$.
Why exactly is that?