Given any group $ G $ of $ n \times n $ complex matrices there is a natural $ n $ dimensional representation of $ G $ on $ V=\mathbb{C}^n $. In this case the representation $$ V \otimes V^* \cong \mathfrak{gl}(V) $$ can be naturally viewed as $ G $ acting by conjugation on the $ n^2 $ dimensional space of all $ n \times n $ complex matrices. Whenever $ G $ is compact then one the direct summands in the decomposition of $ V \otimes V^* \cong \mathfrak{gl}(V) $ will always be the complexification of the adjoint representation of $ G $.
For example, consider the natural module $ (SU_n, V=\mathbb{C}^n) $. Then $ V \otimes V^* \cong \mathfrak{gl}(V) $ decomposes as the $ n^2-1 $ dimensional adjoint irrep $ \mathfrak{sl}_n(\mathbb{C}) $ (which is the complexification of $ \mathfrak{su}_n $) together with a 1 dimensional trivial irrep (the span of the identity matrix $ \sum_{i=1}^n e_i \otimes e_i^* $).
For the natural module $ (SO_n, V=\mathbb{C}^n) $ I'm curious about the direct sum decomposition of $ V \otimes V^* \cong \mathfrak{gl}(V) $ since it is $ n^2 $ dimensional it must include a lot of other interesting stuff beyond the $ \frac{n(n-1)}{2} $ dimensional adjoint representation.
Similarly, for the natural module $ (Sp_n, V=\mathbb{C}^{2n}) $ I'm curious about the direct sum decomposition of $ V \otimes V^* \cong \mathfrak{gl}(V) $ since it is $ 4n^2 $ dimensional it must include a lot of other interesting stuff beyond the $ n(2n+1) $ dimensional adjoint representation.
I'm sure all this is well known, so I would also be happy to accept a reference.