Eigenvalues are not syllabus. So, can this question be explained without the concept of eigenvalues?
Here's a proof that does not need the notion of characteristic polynomials or eigenvalues. It does need the notion of a fixed point and some sophistication with orthogonality.
lemma: $A$ has no non-zero fixed points
proof: $A\mathbf x = \mathbf x\implies -\mathbf x=-I \mathbf x = A^2\mathbf x = A\big(A\mathbf x\big) = A \big(\mathbf x\big) = \mathbf x \implies 2\mathbf x = \mathbf 0\implies \mathbf x =\mathbf 0$
(note this can be interpreted in terms of eigenvalue 1 but such interpretation isn't needed; a fixed point is really a general and very useful concept that shows up in topology and analysis.)
special case: Orthogonal A
Then $A$ is skew symmetric because $A = A^{-1}A^2 =A^TA^2 =A^T(-I) = -A^T$
checking the determinant
$0\neq \det\big(A\big)=\det\big(A^T\big)=\det\big(-I_n A\big)=\det\big(-I_n\big)\det\big( A\big)=(-1)^n\det\big(A\big)\implies \text{n is even}$
Since $A$ is orthogonal it may be decomposed into $m$ Householder reflection matrices $H_k$, each of the form $H_k:=1 -2\mathbf x_k\mathbf x_k^T$ for some length one $\mathbf x_k$, for some $m\in\big\{1,2,\dots, n-1,n\big\}$.
Since $\det\big(H_k\big)=-1$ (e.g. by matrix determinant lemma) this us that
$\det\big(A\big)=-1\implies m \text{ is odd}$ and $\det\big(A\big)=1\implies m \text{ is even}$
now suppose for contradiction that $\det\big(A\big)=-1$. We have
$\det\big(A\big)=-1\implies m \text{ is odd}\implies m\lt n$ since $n$ is even. Thus write
$A =H_1H_2\cdots H_{m-1}H_m =\prod_{k=1}^m H_k$
and collect $ M:= \bigg[\begin{array}{c|c|c|c|c|c|c}
\mathbf x_1 &\mathbf x_2 & \cdots & \mathbf x_m
\end{array}\bigg]$
then there is some $\mathbf y\neq \mathbf 0$ orthogonal to all these $\mathbf x_k$
proof: apply rank-nullity to $M^T$. Now
$H_k\mathbf y =\big(I -2\mathbf x_k\mathbf x_k^T\big)\mathbf y = \mathbf y -2\mathbf x_k(\mathbf x_k^T\mathbf y) = \mathbf y -\mathbf 0=\mathbf y$
so $\mathbf y$ is a fixed point for these $H_k$ thus
$A\mathbf y = \prod_{k=1}^m H_k\mathbf y= \prod_{k=1}^{m-1} H_k\mathbf y=\cdots = \prod_{k=1}^2 H_k\mathbf y = H_1\mathbf y =\mathbf y$
so $A$ has a non-zero fixed point, which is a contradiction.
conclude m is even and $\det\big(A\big)=1$
general case
$A$ is similar to orthogonal matrix $A'$, so $S^{-1}AS= A'$
proof: $A$ is real matrix and for some $k\geq 2,A^{k}$ is similar to an orthogonal matrix,how to prove $A$ is also similar to an orthogonal matrix?
where of course $(A')^2=(S^{-1}AS)^2=S^{-1}A^2S= S^{-1}(-I)S = -I$ so the above argument proves $\det\big(A'\big)=1$ and similar matrices have the same determinant so $\det\big(A\big)=1$.