I'm 10 years late for this 2013 party, but better late than never. Yes, there is another closed-form value of $\operatorname{erf}(x)$. This is,
$$\operatorname{erf}\Big(\sqrt{\tfrac12}\Big)=1-\frac{\Gamma\big(\tfrac12,\tfrac12\big)}{\Gamma\big(\tfrac12\big)}=0.68268949\dots$$
the decimal expansion of which is https://oeis.org/A178647. This was found using a beautiful identity by Ramanujan (which I was coincidentally investigating),
$$\sqrt{\frac{\pi\,e}{2}}
=1+\frac{1}{1\cdot3}+\frac{1}{1\cdot3\cdot5}+\frac{1}{1\cdot3\cdot5\cdot7}+\dots\color{blue}+\,\cfrac1{1+\cfrac{1}{1+\cfrac{2}{1+\cfrac{3}{1+\ddots}}}}$$
Since $\Gamma\big(\tfrac12\big)=\sqrt{\pi}$ and the series and continued fraction have closed-forms, Ramanujan's identity can also be expressed in two ways,
\begin{align}
\Gamma\big(\tfrac12\big)\sqrt{\frac{e}{2}}
&= \,\sqrt{\frac{e}{2}} \times\,\Gamma\big(\tfrac12\big)\,\operatorname{erf}\Big(\sqrt{\tfrac 12}\Big) \;\color{blue}+\; \sqrt{\frac{e}{2}} \times\,\Gamma\big(\tfrac12\big)\left(1-\operatorname{erf}\Big(\sqrt{\tfrac 12}\Big)\right)\\
&= \sqrt{\frac{e}{2}}\times\Big(\Gamma\big(\tfrac12\big)-\Gamma\big(\tfrac12,\tfrac12\big)\Big) \color{blue}+\, \sqrt{\frac{e}{2}}\times\Big(\Gamma\big(\tfrac12,\tfrac12\big)\Big)
\end{align}
where the first way is in this post, and the second in this post. Equating the first addends,
$$\Gamma\big(\tfrac12\big)\,\operatorname{erf}\Big(\sqrt{\tfrac 12}\Big) = \Gamma\big(\tfrac12\big)-\Gamma\big(\tfrac12,\tfrac12\big)$$
one can then easily solve for $\operatorname{erf}(x)$.