The answer is that there are no more regular polygons whose diagonal-to-side ratio is a metallic mean. Here is a quick proof (omitting some details since I don't have time right now, I can come back to fill them in later).
The metallic means are quadratic irrationals, i.e. numbers of algebraic degree 2. On the other hand, as stated in the question, for a given number of vertices $n>2$ we have that the $(m-1)$th diagonal-to-side ratio is
$$d_m=\frac{\sin(\pi m/n)}{\sin(\pi/n)}=e^{\pi i(1-m)/n}\frac{e^{2\pi i m/n}-1}{e^{2\pi i/n}-1} =$$
$$=e^{\pi i(1-m)/n} \left( 1 + e^{2\pi i/n} + \cdots + e^{2\pi i(m-1)/n}\right) = e^{\pi i(1-m)/n} + e^{\pi i(3-m)/n} + \cdots + e^{\pi i(m-1)/n},$$
where we take $1<m<n-1$ to avoid trivial cases. First consider the case of $m$ odd, where all the summands are powers of $e^{2\pi i/n}$. Let $G$ be the Galois group of the cyclotomic field $\mathbb{Q}(e^{2\pi i/n})$. Using modular arithmetic, it is straightforward to see that this sum of roots of unity is left invariant by no element of $G$ other than complex conjugation (except in the cases $m=1$ or $m=n-1$, which we excluded). This means that the algebraic degree of $d_m$ is $\varphi(n)/2$, where $\varphi$ is Euler's totient function.
In the case of $m$ even, similar considerations lead us to the algebraic degree of $d_m$ being $\varphi(2n)/2$.
It is easy to check, using Euler's product formula, that the only numbers with $\varphi(n)/2=2$ are $5, 8, 10$ and $12$. For $n=5, 10$ (pentagon and decagon) we get (integral linear combinations of 1 and) the golden mean
$$\phi = \frac{1+\sqrt5}{2} = [1;1,1,1,1,1,1,1,\ldots],$$
where $[a_0;a_1,a_2,\ldots]$ denotes a continued fraction. For $n=8$ (octagon) we get the silver mean
$$\delta_S = 1+\sqrt2 = [2;2,2,2,2,2,2,2,\ldots],$$
and for $n=12$ (dodecagon) we get a nameless gold-silver "alloy"
$$\delta_A = 1+\sqrt3 = [2;1,2,1,2,1,2,1,\ldots],$$
which is not a metallic mean per se. Similarly, the only numbers with $\varphi(2n)/2=2$ are $4, 5$ and $6$. We already dealt with the case $n=5$; in the two remaining cases we just get $\sqrt2$ and $\sqrt3$. This exhausts the list of possibilities.