First, if $X_1, X_2, \ldots, X_n$ are IID random variables with common distribution $X$ and moment generating function $M_X(t) = \operatorname{E}[e^{tX}]$, then $$S_n = \sum_{i=1}^n X_i$$ has moment generating function $$M_{S_n}(t) = \operatorname{E}[e^{tS_n}] = \operatorname{E}[e^{t\sum_{i=1}^n X_i}] = \operatorname{E}\left[\prod_{i=1}^n e^{tX_i}\right] \overset{\text{ind}}{=} \prod_{i=1}^n \operatorname{E}[e^{tX_i}] = \prod_{i=1}^n M_X(t) = (M_X(t))^n.$$ That is to say, the MGF of a sum of $n$ IID random variables is equal to the MGF of one such random variable raised to the $n^{\rm th}$ power.
It follows from this that if $X \sim \operatorname{Exponential}(\lambda)$, where $\lambda$ is a rate parameter, then $$M_X(t) = \frac{\lambda}{\lambda - t}.$$ Your problem is the special case $\lambda = 1$. Therefore, $$M_{S_n}(t) = \left(\frac{\lambda}{\lambda - t}\right)^n,$$ where we have defined $S_n$ as the sample total as described above. How does this help us with the MGF of $Y_n$? Well, we know $$Y_n = \sqrt{n}(\bar X_n - 1).$$ We also know that $$\bar X_n = S_n/n,$$ that is to say, the sample mean is simply the sample total divided by the sample size $n$. Thus, $$M_{Y_n}(t) = \operatorname{E}[e^{t(\sqrt{n}(\bar X_n - 1))}] = \operatorname{E}[e^{(t/\sqrt{n})S_n - t\sqrt{n}}] = \operatorname{E}[e^{(t/\sqrt{n}) S_n}] \operatorname{E}[e^{-t\sqrt{n}}] = e^{-t\sqrt{n}} M_{S_n}(t/\sqrt{n}).$$ The first equality is the definition of MGF. The second follows from simple algebraic manipulation of the exponent. The third is the result of factoring out the non-random term $e^{-t\sqrt{n}}$, which is not a function of any random variable, and the fourth is the definition of MGF again. Finally, we use the earlier result for $M_{S_n}(t)$ to get $$M_{Y_n}(t) = e^{-t\sqrt{n}} \left(\frac{1}{1 - t/\sqrt{n}}\right)^n.$$
To find the limiting distribution of $Y_n$, you need to evaluate $$\lim_{n \to \infty} M_{Y_n}(t).$$ This should give you $e^{t^2/2}$, but I have left the proof as an exercise. What familiar distribution has such an MGF? Why does this make sense?