Let $\Omega$ be the sample space, $p: \Omega \rightarrow [0,1]$, be any function satisfying $\sum_{w\in\Omega} p(w) = 1$. Then there is a valid probability triple $(\Omega, \mathcal{F},P)$, where $\mathcal{F}$ is the collection of all subsets of $\Omega$ (the power set), and for $A \in \mathcal{F}, P(A) = \sum_{w\in A} p(w)$.
My question is why/how we know that, when $\Omega$ is finite or countable, a probability measure can be defined over ALL possible subsets (vs, say, the fact that a probability measure -- satisfying the standard axioms, of course -- cannot be defined over all subsets of [0,1]). Is there a proof of this somewhere (if so, please let me know where I can look), or could someone provide one?