I assume you are talking about List<T> and EntityCollection<T> which is used by the Entity Framework. Since the latter has a completely different purpose (it's responsible for change tracking) and does not inherit List<T>, there's no direct cast.
You can create a new EntityCollection<T> and add all the List members.
var entityCollection = new EntityCollection<TEntity>();
foreach (var item m in list)
{
entityCollection.Add(m);
}
Unfortunately EntityCollection<T> neither supports an Assign operation as does EntitySet used by Linq2Sql nor an overloaded constructor so that's where you're left with what I stated above.