Are there any "realistic" examples of topological spaces that are not metric spaces. You are free to invent your own definition of "realistic". But, at a minimum, a realistic example is one that occurs naturally as part of some other problem, not something that is fabricated to provide a counterexample or a topology homework exercise. One good example is the topological vector space of all functions $f:\mathbb{R} \to \mathbb{R}$ under pointwise convergence. Any others?
If such examples are difficult to find, maybe there are results in the opposite direction: are there results that say something like "every topology that satisfies conditions X, Y, Z can be generated from a metric"? One example: a compact Hausdorff space is metrizable if and only if it is second-countable. Any other theorems like that?
Edit
I found this page, which does a pretty good job of answering my second question. So, that just leaves the first one.