Given a compact manifold and a Morse function, we obtain a convenient cellular decomposition. But suppose I have a (finite dimensional, possibly singular) space $X$ that is not a manifold and I wish to find a simplicial set $S$ whose geometric realization is homeomorphic to $X$. Surely no tool will be as convenient as Morse theory, but there ought to be techniques that are similarly explicit.
Here's a test question that should be easy if the tool is good enough.
Let $G$ be a finite dimensional connected Lie group, and define $T_G$ to be the subspace of $G \times G$ consisting of commuting pairs $T_G = \left\{ (g,h) \in G \times G \; \; | \; \; gh=hg \right\}$. Supposing that $T_G$ is connected, does there exist a reduced simplicial set $S$ with simplicial subset $S_0 \subseteq S$ so that the geometric realization of $S$ is homeomorphic to $G \times G$ and the geometric realization of $S_0$ is the subspace $T_G$?
Note that the connectivity of $G$ makes it plausible for $S$ to be reduced. More generally, if a space is $n$-connected, it would be nice if we could assume the simplicial set to have a trivial $(n-1)$ skeleton.