One way is to exhibit an isomorphism directly. So consider the map $\phi:2\Bbb Z/6\Bbb Z \to \Bbb Z_3$ given by:
$\phi(2k + 6\Bbb Z) = k \text{ (mod }3)$
One caveat: when we define a map on an equivalence class by using "representatives" we need to be sure we get the same result no matter which representative we choose. Put another way, we need to show that if for two integers $k,k'$ we have:
$2k + 6\Bbb Z = 2k' + 6\Bbb Z$
then we need to be sure that $\phi$ gives us the same image, that is that:
$k \equiv k' \text{ (mod }3)$.
It should be clear that $2k + 6\Bbb Z = 2k' + 6\Bbb Z$ if and only if $2k - 2k'$ is a multiple of $6$. Now if: $2k - 2k' = 6t$, for some integer $t$, we have that $2(k - k') = 6t$, so that $k - k' = 3t$, which is precisely what it means for $k$ and $k'$ to be congruent modulo $3$.
All this is to be sure that $\phi$ is a "well-defined" function on the cosets, even though we are using elements of the cosets to define the value of $\phi$ at a coset.
With that bit out of the way, the rest is downhill:
$\phi((2k + 6\Bbb Z) + (2m + 6\Bbb Z)) = \phi((2k+2m) + 6\Bbb Z)$
$= \phi(2(k+m) + 6\Bbb Z) = (k+m) \text{ (mod }3) = k \text{ (mod }3) + m \text{ (mod }3)$
$= \phi(2k + 6\Bbb Z) + \phi(2m + 6\Bbb Z)$, so $\phi$ is a homomorphism, and the correspondence:
$0 + 6\Bbb Z \mapsto 0 \text{ (mod }3)$
$2 + 6\Bbb Z \mapsto 1 \text{ (mod }3)$
$4 + 6\Bbb Z \mapsto 2 \text{ (mod }3)$
makes it clear $\phi$ is bijective.