There is no such field $F$. Suppose otherwise. Choose any $x \in \mathbb{R}-F$, so $\{1,x\}$ is a basis of $\mathbb{R}$ over $F$. Since the degree of the extension equals $2$, there is a polynomial $x^2 + ax + b = 0$ with coefficients $a,b \in F$. By the quadratic formula, $x$ is an $F$-linear combination of $1$ and $\sqrt{y}$ for some $y \in F$ and $y$ must be positive since $x$ is real. It follows that $\{1,\sqrt{y}\}$ is a basis of $\mathbb{R}$ over $F$.
Consider $z = \sqrt[4]{y} \in \mathbb{R}$, $z>0$. We can write $z = a + b \sqrt{y}$ where $a,b \in F$. Solving for $a,b$ in the equation $z^2 = \sqrt{y}$ we obtain $a^4 = -\frac{1}{4} y$. However, a negative number has no fourth roots in $\mathbb{R}$, contradiction.