(I am using $f: X \to Y$ as this should also hold for arbitrary metric spaces $X$ and $Y$, the definition of $\alpha$-Hölder-continuous becomes “$\exists L < \infty$ with $d\big( f(x_0), f(x_1) \big) \leq L \cdot d( x_0, x_1 )^\alpha$ for all $x_0,x_1 \in X$”.)
We now need $X$ to have the property that any two points are connected by a $\beta$-Hölder-continuous path for $\beta > \frac{1}{\alpha}$. (Note that this is a slightly weaker condition than requiring the path to be Lipschitz, which in turn is equivalent to it having finite-length/being rectifiable)
Assume we have $\alpha > 1$, $f: X \to Y$ $\alpha$-Hölder-continuous, and two points $x_0 \neq x_1 \in X$ such that there exists some $\beta$-Hölder-continuous path $\gamma$ between them with $\beta > \frac{1}{\alpha}$. We will show that this implies $f(x_0) = f(x_1)$:
By our requirement on $\gamma$ there exists a constant $C < \infty$ such that $d\big( \gamma(t), \gamma(r) \big) \leq C \cdot d( x_0, x_1) \cdot |t-r|^\beta$ for all $t,r \in [0,1]$.
Let us define $g: [0,1] \to \mathbb{R}$ as
$$ g(t) := \frac{ d\big( f(x_0), f(\gamma(t)) \big) }{ L \cdot d( x_0, x_1 )^\alpha }. $$
We now have, for any $t,r \in [0,1]$,
$$\begin{align}
| g(t) - g(r) | &= \frac{\left| d\big( f(x_0), f(\gamma(t)) \big) - d\big( f(x_0), f(\gamma(r)) \big) \right|}{ L \cdot d(x_0, x_1)^\alpha } \\
&\leq \frac{d\big( f(\gamma(t)), f(\gamma(r)) \big)}{ L \cdot d( x_0, x_1 )^\alpha } \\
&\leq \frac{ L \cdot d\big( \gamma(t), \gamma(r) \big)^\alpha }{ L \cdot d(x_0, x_1)^\alpha } \\
&\leq \frac{ L C^\alpha \cdot d(x_0, x_1)^\alpha \cdot |t-r|^{\alpha\beta} }{ L \cdot d(x_0, x_1)^\alpha } \\
&=C^\alpha \cdot |t-r|^{\alpha\beta}
\end{align}$$
(here we first used the triangle-inequality and then twice Hölder-continuity)
We see that $g: [0,1] \to \mathbb{R}$ is $\alpha\beta$-Hölder-continuous,
with $\alpha\beta > \frac{\alpha}{\alpha} = 1$, so by the known result it is constant on $(0,1)$, and therefore also constant on $[0,1]$.
Therefore we have
$$ g(0) = \frac{ d\big( f(x_0), f(x_0) \big) }{ L \cdot d( x_0, x_1 )^\alpha } = 0 = g(1) = \frac{ d\big( f(x_0), f(x_1) \big) }{ L \cdot d( x_0, x_1 )^\alpha } $$
implying
$$ 0 = d\big( f(x_0), f(x_1) \big) \quad\iff\quad f(x_0) = f(x_1) .$$