One of the "axioms of probability", or standard definitions from measure theory, is that the probability measure is countably additive over disjoint unions, i.e. if $P: \mathcal{F} \mapsto[0,1]$ is to be a probability measure, and $A_1,A_2,... \in \mathcal{F}$ so that $A_i \cap A_j = \emptyset$ for all $i \ne j$, then we must have $$ P(\cup_{i=1}^\infty A_i) = \sum_{i=1}^\infty P(A_i). $$ Of course this assumption along with the assumption that the probability of the sample space is one will imply finite additivity over unions of disjoint sets, which is more natural and easier to understand I argue, because in many cases, for instance if $\mathcal{F}$ is finite, we could check this assumption on any function $P$ manually. Assuming countably infinite additivity seems to be a big leap.
When discussing this with e.g. students who are in their first year of a math major (and nowhere near measure theory), I often justify the importance of this assumption by saying that it implies a certain "consistency" of $P(\cdot)$. For instance if we were to rewrite any set $A = \cup_i A_i = \cup_i B_i$, where $A_i$ and $B_i$ are different, disjoint, partitions of $A$, countable additivity will imply that $$ \sum_{i=1}^\infty P(A_i) = P(A) = \sum_{i=1}^\infty P(B_i). $$ In otherwords the probability of $A$ will not depend on how we chop up the set $A$. Since in many simple cases, e.g. probabilities on subsets of $[0,1]$ or drawing a venn diagram in the plane, it is easy to imagine countable ways of chopping up sets into disjoint pieces, this seems like an important thing to assume. This also helps reinforce the comparison of probability to "volume" or "area", which of course is the concept that measure theory aims capture.
Another important consequence of this is ``continuity of a probability measure", e.g. if $A_1 \subseteq A_2 \cdots $ and $B = \cup_i A_i$ then $$ \lim_{n\to \infty }P(A_n) = P(B), $$ which is extremely useful. But this later fact is well beyond what would justify this assumption to a beginner.
So now comes the question: what argument would you give to a beginner to explain why the assumption of countable additivity is worth the "cost"? What obvious drawbacks are there to only assuming finite additivity that would convince a (novice) skeptic that it would not lead to nice probability theory?