Here is a proof using the implicit differentiation.
Remarks. I tried this approach yesterday but was stuck at the proof of $F'(c) > 0$. Now I can proceed. I learned this approach some years ago from @G.Kós's answer for this question. By the way, I noticed that @Macavity has tried this way as well.
Let $a_1 := 1 + (\mathrm{e} - 2)a$
and $b_1 := 1 + (\mathrm{e} - 2)b$.
Then $a_1, b_1 > 0$ are two distinct real roots of $f(x) = c$ given that $0 < c < 1$. We need to prove that
$$1 < \frac{a_1 + b_1 - 2}{\mathrm{e} - 2} + 2c < 2. \tag{1}$$
WLOG, assume that $a_1 < b_1$.
Since $f(x)$ is strictly increasing on $(0, 1)$ and strictly decreasing on $(1, \infty)$, and $\lim_{x\to 0^{+}} f(x) = 0$, and $f(x) \le 0$ for all $x \ge \mathrm{e}$, we have $0 < a_1 < 1 < b_1 < \mathrm{e}$.
For $0 < c < 1$, the two real roots $a_1 = a_1(c)$ and $b_1 = b_1(c)$ are functions of $c$ satisfying
$$a_1(c) - a_1(c) \ln a_1(c) =
b_1(c) - b_1(c) \ln b_1(c) = c.$$
By implicit differentiation, we have
$$a_1'(c) - a_1'(c)\ln a_1(c) - a_1(c) \frac{1}{a_1(c)}a_1'(c) = 1, $$
and
$$b_1'(c) - b_1'(c)\ln b_1(c) - b_1(c) \frac{1}{b_1(c)}b_1'(c) = 1$$
which result in
$$a_1'(c) = -\frac{1}{\ln a_1(c)},
\quad b_1'(c) = - \frac{1}{\ln b_1(c)}.$$
Now, let
$$F(c) := \frac{a_1(c) + b_1(c) - 2}{\mathrm{e} - 2} + 2c.$$
We have
$$
F'(c) = \frac{a_1'(c) + b_1'(c)}{\mathrm{e} - 2} + 2
= \frac{-\frac{1}{\ln a_1(c)} - \frac{1}{\ln b_1(c)}}{\mathrm{e} - 2} + 2
> 0. \tag{2}
$$
The proof of (2) is given at the end.
Also, $\lim_{c\to 0^{+}} F(c) = 1$ and $\lim_{c\to 1^{-}} F(c) = 2$.
Thus, we have $1 < F(c) < 2$.
We are done.
Proof of (2).
If $0 < c \le \frac13$,
we have $f(7/3) = \frac73 - \frac73 \ln \frac73 > \frac13 \ge c = f(b_1(c))$ which results in $b_1(c) \ge \frac73$. Thus, we have
$$\frac{-\frac{1}{\ln a_1(c)} - \frac{1}{\ln b_1(c)}}{\mathrm{e} - 2} + 2 > \frac{ - \frac{1}{\ln b_1(c)}}{\mathrm{e} - 2} + 2 \ge \frac{ - \frac{1}{\ln \frac73}}{\mathrm{e} - 2} + 2 > 0.$$
If $c > \frac13$,
we have $f(1/10) = \frac{1}{10} - \frac{1}{10}\ln \frac{1}{10} < \frac13 < c = f(a_1(c))$ which results in
$a_1(c) \ge \frac{1}{10}$. Using $a_1(c) + b_1(c) \ge 2$ (the proof is given in my previous answer), we have
$$\frac{-\frac{1}{\ln a_1(c)} - \frac{1}{\ln b_1(c)}}{\mathrm{e} - 2} + 2
\ge \frac{-\frac{1}{\ln a_1(c)} - \frac{1}{\ln [2 - a_1(c)]}}{\mathrm{e} - 2} + 2 \ge \frac{-\frac43}{\mathrm{e} - 2} + 2 > 0$$
where we use $-\frac{1}{\ln u} - \frac{1}{\ln (2-u)} \ge - \frac43$ for all $1/10 \le u < 1$ (the proof is given at the end).
We are done.
Proof of $-\frac{1}{\ln u} - \frac{1}{\ln (2-u)} \ge - \frac43$ for all $1/10 \le u < 1$.
After clearing the denominators, it suffices to prove that
$$G(u) := -4\ln u \ln (2 - u) + 3\ln u + 3\ln (2 - u) \ge 0.$$
Let $H(u) := G'(u)u(2-u)$. We have
$$H''(u) = \frac{8(1-u)}{u(2-u)} > 0.$$
Also, $H(1) = 0$ and $H(1/10) < 0$. Thus,
$H(u) \le 0$ on $[-1/10, 1)$.
Thus, $G'(u) \le 0$ on $[-1/10, 1)$.
Also, $G(1) = 0$. Thus, $G(u) \ge 0$ on $[-1/10, 1)$.
We are done.