Let $X$ be a well-based space with countable pseudocharacter.
Let $x$ be a point of $X$. As $X$ is well-based, then $x$ has a neighborhood base, let's denote as $\mathcal{B}$, totally ordered by reverse inclusion. And, as $X$ has countable pseudocharacter, then exists $\{A_n\}_{n \in \mathbb{N}}$ collection of open sets such that $\bigcap_{n \in \mathbb{N}}A_n = \{x\}$.
For each, $n \in \mathbb{N}$, exists $B_n \in \mathcal{B}$ such that $B_n \subseteq A_n$. $\{B_n\}_{n \in \mathbb{N}}$ is countable, totally ordered by reverse inclusion and it verifies that $\bigcap_{n \in \mathbb{N}}B_n = \{x\}$.
Let $A$ be a neighborhood of $x$. Then exists $B \in \mathcal{B}$ such that $B \subseteq A$. Suppose that doesn't exist $B_n \in \{B_n\}_{n \in \mathbb{N}}$ such that $B_n \subseteq B$. Then, $B \subsetneq B_n$, for all $n \in \mathbb{N}$, and $B \subseteq \bigcap_{n \in \mathbb{N}}B_n = \{x\}$. As a result, we conclude that $B = \{x\}$.
Therefore, $X$ is first countable.
Edit:
The idea has been the following one:
Given a point of the space, considering a neighborhood base that is totally ordered by reverse inclusion, with the aim of taking a countable subcollection of elements from it verifying that their intersection is such point. This can be done as the space is well-based and has countable pseudocharacter. If this subfamily is a neighborhood base of the point, we are done. But, if it isn't, it means that there is a neighborhood of the point that doesn't contain any element of this subfamily. However, it would contain an element of the base that we have considered at the beginning. As the base is totally ordered by reverse inclusion and this neighborhood doesn't contain any element of the subfamily, then the neighborhood is contained in each element of the family and, therefore, it is also contained in the intersection of all the elements of the subfamily, which is the point. We conclude that the neighborhood is the point, i.e, the point is isolated. So, the point admits a countable neighborhood base, for example, the basis that has the point itself as its single element.