Let me try to clarify a bit: $\sigma$ already induces an isomorphism as you can see because if we take $\eta\in L$ we can say that: $\sigma : L_{{P_j}}\rightarrow L_{P_k} $ such that $\sigma(\eta)=\eta$ which therefore induces to $\sigma(P_j)=P_k$. Therefore, the map $\psi := \sigma|_{L_{P_j}} : L_{P_j}\rightarrow L_{P_k}$ with $K_p$ is fixed because $K_p$ is the identity map such that $\sigma$ is restricted to $K$ with $\sigma\in G(L|K)$. Ultimately, $\psi:L_{P_j}\rightarrow L_{P_k}$ is an isomorphism fixing to $K_p$ as $\sigma = \psi$.
Addressing the further progression:
So, if you consider $P_1=P_j$ we can consider the following completions of the evaluation rings:
$$
\sigma : \widehat{\mathcal{O}(L,vp_1)} \rightarrow \widehat{\mathcal{O}(L,vp_j)}
$$
Since the given isomorphism of $\sigma$ the previous expression can be further expanded as:
$$
\sigma : \widehat{\mathcal{O}(L,\hat{v}p_1)} \rightarrow \widehat{\mathcal{O}(L,\hat{v}p_j)}
$$
Thefore, the expression also fixes
$$
\widehat{\mathcal{O}(K,v_p)} = \mathcal{O}(K_p,\hat{v}_p)
$$
Now, by taking the fraction fields of the completed valuation rings we will have:
$\text{Frac}(\sigma) : L_{P_1}\rightarrow L_{P_j}$ which will fix $K_p$ as $K_p = \text{Frac}(\mathcal{O}(K_p,\hat{v}_p))$ which will ultimately lead us to $v_{P_j}∘\sigma=v_{P_1}$
I hope this answered your question, let me know for any further analysis. Have a nice day!