I don't believe this statement, so I think I'm making a mistake. I've asked ~10 people, and nobody found a mistake in the proof. Here it is.
Let $L/K$ be a Galois extension with Galois group $S_n$. (There are various ways to get such Galois extensions, the most common one uses indeterminates. See Constructing a Galois extension field with Galois group $S_n$.)
Since $L/K$ is a finite and separable extension, there's a primitive element $\alpha$ such that $L = K(\alpha)$.
Then, the minimal polynomial of $\alpha$ has degree $n!$.
The Galois group acts transitively on the roots of the polynomial, and therefore $S_n$ acts transitively on a set of size $n!$.
If this is true, every element of $S_n$ should act differently on every element of the set $\{1,2,...,n!\}$. Even if such an action exists, it's highly counterintuitive.
Edit: @coiso pointed out that $S_n$ acting on itself is transitive and is such an action, which makes sense. I just never put 2 and 2 together and noticed that this means that $S_n$ is a transitive subgroup of $S_{n!}$.