I'm aware of the fact that there exists a natural isomorphism between a vector space $V$ and its double dual $V''$; what I'm asking is the following: let's define an application $F:V\to V'$ as $F(v)=v^T$ (the image of a vector is the application of the dual which corresponds to multiplying to the transpose of said vector); now for every $v\in V$ we can find $F(v)\in V'$ and vice versa, therefore $F$ is an isomorphism. Now I believe that could be considered a natural isomorphism since whatever are the basis for $V$ and $V'$, the coordinates of some vector with respect to said basis are unique and therefore to one vector in $V$ with respect to some basis $\mathscr{B}_V$ corresponds one and only application in $V'$ with respect to some basis $\mathscr{B}_{V'}$, even if $\mathscr{B}_{V'}$ is not the dual basis of $\mathscr{B}_V$.
Why isn't this a natural isomorphism? It seems to me I don't need to chose a basis for either $V$ or its dual in order to make this work...