I was requested to decide whether there is some linear transformation $f: \mathbb{R}^2 \rightarrow \mathbb{R}^4$ satisfying
\begin{equation*} \begin{cases} f(0, 1) &= (1, 2, 0, 0) \\ f(1, 0) &= (1, 1, 0, 0) \end{cases} \end{equation*}
and, if it exists, whether it is unique or not.
It seems perfectly possible that such linear transformation exists. If we assume $f$ is a linear transformation satisfying the aforementioned properties, then it is such that any $f(\textbf{x}) \in \text{Im}(f)$ is of the form
\begin{align*} f(\textbf{x}) &= f\big(x_1(0, 1) + x_2(1, 0)\big) \\ &= x_1f(0, 1) + x_2f(1, 0) \\ &= x_1(1, 2, 0, 0) + x_2(1, 1, 0, 0) \end{align*}
From this would follow $\text{Im}(f) = \{x_1(1, 2, 0, 0) + x_2(1, 1, 0, 0) \mid x_i \in \mathbb{R}\}$, which on its turn implies $\text{Im}(f)$ is isomorphic to $\mathbb{R}^2$. In short, the transformation turns out to be
\begin{align*} f(\textbf{x}) &= (x_1, 2x_2, 0, 0) + (x_2, x_2, 0, 0) \\ &= (x_1 + x_2, 2x_2 + x_2, 0, 0) \end{align*}
We have shown that a linear transformation $f$ satisfies the given equalities if and only if $f(\textbf{x}) = (x_1 + x_2, 2x_2 + x_2, 0, 0)$. Hence $f$ is unique.
I : Is this solution correct? II : What would be an example of non-uniqueness? Restraining ourselves to the same spaces of the problem: what $f_1, f_2$ mapping $\mathbb{R}^2 \rightarrow \mathbb{R}^4$ are such that $f_1(\textbf{x}_1) = f_2(\textbf{x}_1), ..., f_1(\textbf{x}_n) = f_2(\textbf{x}_n)$ for some set of $n$ vectors $\mathbf{x} \in \mathbb{R}^2$? Are such mappings special in any relevant sense, or studied for some particular purpose?