Let $(E, |\cdot|)$ be a normed vector space. Let $E^*, E^{**}$ be the dual and bidual of $E$ respectively. Let $\tau := \sigma(E^*, E^{**})$ and $\tau' := \sigma(E^{*}, E)$ be the weak and weak$^*$ topologies of $E^*$ respectively. If $E \cong E^{**}$, i.e., $E$ is isometrically isomorphic to $E^{**}$, then $\tau = \tau'$. This would be the case if $E$ is a reflexive Banach space or a Hilbert space in particular.
Could you confirm if my understanding is correct?