They have already mentioned and approached to the problem e.g. here There are no semisimple Lie algebras of dimension $4$, $5$, or $7$
We only know, root space decomposition without introducing root system or its classification.
Given complex Lie semi-simple algebra $L$, we have
$$L=H\oplus \bigoplus_{\alpha \in \Phi}L_\alpha$$ $$L_\alpha=\{x\in L:(\forall h\in H)\ [h,x]=\alpha(h)x\}$$ $H$ is Cartan Subalgebra. $\Phi =\{\alpha\neq 0\in H^* \;|\; L_\alpha\neq 0\}$ where $H^*$ is dual space of the Cartan Subalgebra $H$
By above decomposition we can show $$\dim(L)=\dim(H)+\vert\Phi\vert$$
We can also know that $\pm \alpha\in \Phi$ if $\mp \alpha\in \Phi$
That shows $|\Phi|=$ even.
We also know, every semisimple complex Lie Algebra $L$ has a simple subalgebra isomorphic to $\mathfrak {sl}(2,\mathbb C)$
$\bullet$For $dimL=4$:
I can show that $|\Phi|$ can't be $0$ and $4$. Trivially since $L$ is neither abelian, nor $H$ is trivial.
For $|\Phi|=2$, $dimH=2$. Can I say that $L$ would have $\mathfrak {sl}(2,\mathbb C)$ as a subalgebra but it is dimension $3$?
So as you can see I need to show brutely without invoking classifications via $A_n,B_n,G_n$ and root systems. Using basic informations and dimension formula how we can show these dimensions cannot have semisimple complex Lie structre?