By comparison with the binomial expansion of $(1+x)^s$, a sufficient condition for the formula $\sum_{n=0}^\infty{s\choose n}=2^s$ to hold is that $A_s=\sum_{n=0}^\infty{s\choose n}$ is absolutely convergent, since then the binomial expansion of $(1+x)^s$ is normally convergent on $|x|\leq 1$ and represents $(1+x)^s$ for $|x|<1$ - by continuity of both sides of the equation, we get the formula for $|x|=1$.
I manage to prove that $A_s$ is absolutely convergent for real $s\geq 1$. Indeed, then we have with $N=[s]+1$ and $m=[s]\geq 1$ the majorant $$ \sum_{n=0}^\infty\left|{s\choose n}\right|\leq\sum_{n=0}^m\left|{s\choose n}\right|+N!\zeta(m+1)\,. $$ Further, for $s=\frac{1}{2}$, we have by the Wallis product that $\left|{\frac{1}{2}\choose n}\right|\sim\frac{1}{2n\sqrt{\pi n}}$, and we also get the absolute convergence.
For the other values of $s$, I am stuck. The series under consideration should be absolutely convergent for all real $s\geq 0$. However, for $s=-\frac{1}{2}$ the series $A_s$ is convergent but not absolutely convergent by the Leibniz criterion and according to numerical evaluation it indeed represents $2^s$.
Question. For which complex values $s$ does the formula $A_s=2^s$ hold?
Question'. For which complex values $s$ is the series $A_s$ convergent on the nose, not necessarily absolutely convergent?