idea: take $L$ and use very simple (i.e. diagonal matrix) congruence and similarity transforms to make this a result about stochastic matrices which are especially easy to work with; e.g. multiplication by a positive diagonal matrix does not change irreducibility. The same technique can be used to prove e.g. that $\dim \ker L$ gives the number of connected components (because the algebraic multiplicity of the Perron root of a stochastic matrix counts such thing.)
$L=D-A$
where $A$ is the adjacency matrix for your connected graph. Now effect a congruence transform with $D^\frac{-1}{2}$
$ D^\frac{-1}{2}\big(D-A\big)D^\frac{-1}{2}=I -D^\frac{-1}{2}AD^\frac{-1}{2} = I-B$
and congruence of course preserves rank.
$B$ is an irreducible real-non-negative matrix with that single Perron root $\lambda =1$. Using $\Gamma := \text{diag}(\mathbf v)$ the Perron vector of $B$ we see $S:= \Gamma^{-1} B \Gamma $ where $S$ is a stochastic matrix.
Now if you change some diagonal component of $D$ (WLOG the first component) -- by any amount so long as it stays a positive matrix, then this is equivalent to multiplying by
$\Sigma =\begin{bmatrix}
\alpha & \mathbf 0\\
\mathbf 0 & I_{n-1}
\end{bmatrix}$
for $\alpha \in (0,1)$ to decrement and $\alpha \gt 1$ to increment,
side note: if for some reason we wanted to consider the case where $D$ had a non-positive diagonal element it would immediately follow that the 'Laplacian' was no longer PSD, giving the result.
essentially running through the same steps as before:
$L\to L'=\Sigma D - A$ and the congruence transform now gives us
$I -\Sigma^\frac{-1}{2} D^\frac{-1}{2}AD^\frac{-1}{2}\Sigma^\frac{-1}{2} = I-\Sigma^\frac{-1}{2} B\Sigma^\frac{-1}{2}=I-B'$
$S':= \Gamma^{-1}B' \Gamma= \Gamma^{-1}\Big(\Sigma^\frac{-1}{2} B\Sigma^\frac{-1}{2}\Big) \Gamma=\Sigma^\frac{-1}{2}\Big( \Gamma^{-1} B \Gamma\Big)\Sigma^\frac{-1}{2} = \Sigma^\frac{-1}{2} S \Sigma^\frac{-1}{2}$
(since diagonal matrices commute). By design $S'$ is no longer stochastic and we can exploit this. In particular
if $\alpha \in (0,1)$ then the row sum in the first row increases and it does not decrease in any other row. And if $\alpha \gt 1$ then the first row sum decreases and it does not decrease in any other row.
Finally Perron-Frobenius theory tells us that for an irreducible non-negative matrix
$\text{min row sum }S' \leq \text{Perron root }S' \leq \text{max row sum }S'$
and both inequalities are strict unless $\text{min row sum } = \text{max row sum }$ (which was the case with stochastic $S$ and is not the case with $S'$). Thus we recover Perron root $\lambda \gt 1$ for $\alpha \in(0,1)$ and Perron $\lambda \in (0,1)$ for $\alpha \gt 1$. This is preserved under similarity transform back to $B'$ and of course the mapping to $I-B'$ is $\lambda \to 1-\lambda$, and congruent matrices have the same signature which gives the result for $L'$.