You have a fundamental, but very common, misconception about physical measurements. There is no such thing as a physical object of exactly length $\pi$, no matter what the unit-of-measure for length. Not $\pi$ meters, not $\pi$ feet, not $\pi$ femtofurlongs.
But this is not because $\pi$ is irrational. There is also no such thing as a physical object of length exactly $1$. The actual cause is that physical measurements are not defined to perfect accuracy. Once you start looking close enough, the very definition of what you are measuring no longer makes sense. At a macroscopic scale, the boundaries of the object seem quite precise. But by the time you get to the atomic scale, they are not clear at all. Is this atom a part of the object or not? The distinction becomes fuzzy. Physical objects exchange molecules with their environment constantly.
Look a little closer, and the picture becomes even less clear. So you've decided this atom is part of the object. But what counts as "inside" the atom and thus part of the object, and what counts as out? You cannot decide by particle position, because the particles do not have well-defined positions. Instead they exist in a quantum-mechanical smear.
All physical measurements suffer similar drawbacks. There is some limit to their precision. This limit is not just because of our inability to measure more precisely, but also because the quantities we are measuring are not even well-defined below some level. The only measurements we know precisely are either because they are fundamentally discrete and thus can only take on certain values ("I have 2 eyes") or else because we have defined the units they are being measured in to enforce a specific value. Thus we know exactly what the speed of light in a vacuum is in meters per second. Instead it is what constitutes a "meter" and a "second" that are a bit fuzzy.
So no, you cannot divide the area of a piece of land by exactly $2.25$ or even by exactly $2$, any more than you can divide it exactly by $\pi$. The area of the piece of land is not exact in and of itself, so neither can any division of it be.
The physical universe is not mathematical in nature. Rather, mathematics is a tool we can use to model it. But those models are at best approximate representations. They cannot reflect it exactly.