For some common categories, there are nice characterizations of their opposite category: ie any group is isomorphic to it's opposite, $\mathbf{Set}^{\text{op}}$ is equivalent to the category of complete atomic boolean algebras and $\mathbf{CRing}^{\text{op}}$ is equivalent to the category of affine schemes. This question also asks about a description of the opposite category of $\mathbf{Top}$, also has some interesting answers.
Is there a nice characterization of $\mathbf{Grp}^{\text{op}}$ (ie as some simple concrete category)? Has this category been studied, and if yes, what are some references about its properties?