I am studying Morse Theory on finite dimensional and compact manifolds using homology groups and relative homology groups on $\mathbb{Z}$. I want to show that this theory could be developed using De Rham cohomology and relative cohomology. What I'd like to ask you is if it's true that $ \forall k \in \{0,...,dim (\mathcal{M}) \}$ and $\forall \, A \subset \mathcal{M}, \, H_k(\mathcal{M},A) \cong H^k (\mathcal{M},A)$. Regarding the same relation between 'absolute' homology and cohomology, I know the Poincaré Duality $H_k (M) \cong H_{n-k}(M) \cong (H^{n-k}(M))^*$ and $(H^{n-k}(M))^* \cong H^{n-k}(M)$ (dim $\mathcal{M} < \infty$) (Is the previous sequence of isomorphisms correct? I might be wrong due to my inexperience in this topic). If this is correct, can I generalize it to Topological couples and consequently to relative homology? How can I prove this?
Thank you for your time.