Is there a first-order formula ϕ(x) with exactly one free variable $x$ in the language of fields together with the unary function symbol $\exp$ such that in the standard interpretation of this language in $\Bbb C$ (where $\exp$ is interpreted as the exponential function $x \mapsto e^x$), $ϕ(x)$ holds iff $x \in \Bbb R$?
My thoughts: If one takes the algebraic theory of the complex field without the exponential function, then $\Bbb R$ is not definable because there are isomorphisms of $\Bbb C$ mapping reals to non-real numbers. Does a similar approach work in this case? In particular, is there any other isomorphism of the exponential $\Bbb C$ structure besides the identity and complex conjugation?
$$z\in\mathbb Q\iff\exists a\colon\exp(a)=1\land a\ne 0\land \exp(za)=1$$ This is because this implies that $a$ and $za$ are both integer multiples of $2\pi i$.
– Hagen von Eitzen Jun 12 '13 at 16:16