In Nash & Sen p.162, they show that the space of all positive definite symmetric matrices $C$, while not a vector space itself, is homeomorphic to the space of all symmetric matrices $S$ (which is a vector space), via the map
$$ s \rightarrow e^s \in C, s \in S $$
My question: can I not make $C$ into a vector space by defining addition of two elements as first adding the elements in $S$ and then exponentiating, i.e. $ e^a + e^b \equiv e^{a + b}$? Note this is not the usual multiplication of matrices. It seems to me that we then have an inverse ($e^{-a}$) and an identity element ($e^0$), that we inherit commutativity etc. from $S$, and we can define scalar multiplication in the usual way.
More generally, why is something homeomorphic to a vector space not itself a vector space?
Can someone tell me where I'm going wrong?