This question follows up another question on this website.
Let $M$ be a Riemannian manifold and let $f : M \rightarrow \mathbb R$ be a smooth function. We assume that $\nabla$ is a connection over that manifold. The Hessian of $f$ is the symmetric tensor
$\operatorname{Hess} f = \nabla \nabla f$
The Levi-Civita connection seems to be symmetric, as can be seen from its definition in terms of Christoffel symbols. see Wikipedia article
Question Under which circumstances the covariant Hessian is a symmetric tensor? Is there an intrinsic way of seeing that the Levi-Civita connection is symmetric?