This is not always the case. For example the mapping
$$
\sigma:\frac{a(t)}{b(t)}\mapsto \frac{a(t^2)}{b(t^2)}
$$
is a non-surjective homomorphism from the field $F=\Bbb{R}(t)$ of rational functions to itself. Here $a(t),b(t)$ are arbitrary polynomials.
However, the following general facts do allow us to conclude this in many special cases:
- A homomorphism of fields necessarily has a trivial kernel, and is thus always injective.
- A homomorphism of fields is always linear over the prime field $k$. Therefore by rank-nullity an injective homomorphism is always surjective, if $[F:k]<\infty$.
So if $F$ is a finite extension of $\Bbb{Q}$ or $\Bbb{F}_p$ for some prime number $p$, the claim holds automatically.
It is true in some other cases as well. For example in the cases $F=\Bbb{R}$ and $F=\Bbb{Q}_p$ (= the field of $p$-adic numbers) simply because in those cases the identity mapping is the only automorphism.