You do not tell us what $v_0,\ldots, v_k$ are, but certainly they are noncolinear vectors in some $\mathbb R^N$.
Let $\Delta^k = [0,e_1,\ldots,e_k] \subset \mathbb R^k$ be the standard $k$-simplex, where the $e_i$ are the standard basis vectors of $\mathbb R^k$. It is the set $\{ (x_1,\ldots,x_k) \in \mathbb R^k \mid x_i \ge 0, \sum_{i=1}^k x_i \le 1 \}$. The $x_i$ are the barycentric coordinates of $x = (x_1,\ldots,x_k)$ associated to $e_i$, $x_0 = 1 - \sum_{i=1}^k x_i$ is the barycentric coordinate associated to $0$.
First note that each $k$-simplex is homeomorphic to $\Delta^k$. In fact
$$h : \Delta_k \to [v_0,\ldots, v_k], h(x_1,\ldots,x_n) = (1 - \sum_{i=1}^k x_i)v_0 + \sum x_i v_i$$
is a homeomorphism. Observe that $[v_0,\ldots, v_k]$ is contained in any ambient $\mathbb R^N$ wit $N \ge k$.
This means that it suffices to show that $\Delta^k$ is homeomorphic to the cube $I^k \subset \mathbb R^k$.
Le $Q = \{ (x_1,\ldots,x_k) \mid x_i \ge 0 \text{ for all } i \}$. Consider the norms $\lVert (x_1,\ldots, x_k) \rVert_1 = \sum_{i=1}^k \lvert x_i \rvert$ and $\lVert (x_1,\ldots, x_k) \rVert_\infty = \max_{i=1}^k \lvert x_i \rvert$. Both are continuous real-valued functions on $\mathbb R^k$. Let $B_1$ and $B_\infty$ denote the closed unit balls with respect to these norms, i.e. $B_1 = \{ x \in \mathbb R^k \mid \lVert (x_1,\ldots, x_k) \rVert_1 \le 1\}$, similarly $B_\infty$. Then $\Delta^k = B_1 \cap Q$ and $I^k = B_\infty \cap Q$. Define
$$\phi : \Delta^k \to I^k, \phi(x) = \begin{cases} \dfrac{\lVert x \rVert_1}{\lVert x \rVert_\infty} x \ne 0 \\ 0 & x = 0 \end{cases}$$
$$\psi : I^k \to \Delta^k, \psi(x) = \begin{cases} \dfrac{\lVert x \rVert_\infty}{\lVert x \rVert_1} x \ne 0 \\ 0 & x = 0 \end{cases}$$
It is readily checked that $\psi \circ \phi = id$ and $\phi \circ \psi = id$, thus $\phi$ and $\psi$ are bijections which are inverse to each other. Both maps are obviously continuous in all $x \ne 0$. But they are also continuous in $0$ since
$$\lVert \phi(x) - \phi(0) \rVert_\infty = \lVert \phi(x) \rVert_\infty = \lVert x \rVert_1 = \lVert x - 0 \rVert_1 ,$$
$$\lVert \psi(x) - \psi(0) \rVert_1 = \lVert x - 0 \rVert_\infty .$$
This means that $\phi,\psi$ are homeomorphisms.
Edited:
Usually $\mathbb R^n$ is endowed with the Euclidean norm $\lVert (x_1,\ldots, x_k) \rVert_2 = \sqrt{\sum_{i=1}^k x_i^2 }$ which generates the standard Euclidean topology. It is well-known that all norms on $\mathbb R^n$ are equivalent, i.e. the topology generated by any norm is the Euclidean topology. Therefore, to show that a function $D = \mathbb R^n \to R = \mathbb R^n$ is continuous, we may take any norm $\lVert - \rVert_D$ on the domain $D$ and any norm $\lVert - \rVert_R$ on the range $R$, similarly for maps $\mathbb R^n \to \mathbb R$. However, in the context of this answer we do not need the general norm equivalence theorem. Just note that
$$\lVert (x_1,\ldots, x_k) \rVert_\infty \le \lVert (x_1,\ldots, x_k) \rVert_2 = \sqrt{\sum_{i=1}^k x_i^2 } \le \sqrt n \max_{i=1}^k \lvert x_i \rvert = \sqrt n \lVert (x_1,\ldots, x_k) \rVert_\infty$$
$$\lVert (x_1,\ldots, x_k) \rVert_\infty \le \lVert (x_1,\ldots, x_k) \rVert_1 \le n \lVert (x_1,\ldots, x_k) \rVert_\infty$$