I've ran an exhaustive search (as Ben10's comment suggests) and the first solution was found after around $3\cdot10^5$ potential solution paths were discarded. Below is the found solution.
The labeled hexagon permutations, sorted in two different ways:
Sorted by permutations: Sorted by labels:
([0, 1, 2, 3, 4, 5], 'A') ([0, 1, 2, 3, 4, 5], 'A')
([0, 1, 2, 3, 5, 4], 'B') ([0, 1, 3, 2, 5, 4], 'A')
([0, 1, 2, 4, 3, 5], 'C') ([0, 1, 4, 5, 2, 3], 'A')
([0, 1, 2, 4, 5, 3], 'D') ([0, 1, 5, 4, 3, 2], 'A')
([0, 1, 2, 5, 3, 4], 'E') ([0, 2, 1, 4, 3, 5], 'A')
([0, 1, 2, 5, 4, 3], 'F') ([0, 2, 3, 5, 1, 4], 'A')
([0, 1, 3, 2, 4, 5], 'E') ([0, 2, 4, 1, 5, 3], 'A')
([0, 1, 3, 2, 5, 4], 'A') ([0, 2, 5, 3, 4, 1], 'A')
([0, 1, 3, 4, 2, 5], 'B') ([0, 3, 1, 5, 2, 4], 'A')
([0, 1, 3, 4, 5, 2], 'F') ([0, 3, 2, 4, 5, 1], 'A')
([0, 1, 3, 5, 2, 4], 'C') ([0, 3, 4, 2, 1, 5], 'A')
([0, 1, 3, 5, 4, 2], 'D') ([0, 3, 5, 4, 1, 2], 'A')
([0, 1, 4, 2, 3, 5], 'D') ([0, 4, 1, 3, 5, 2], 'A')
([0, 1, 4, 2, 5, 3], 'C') ([0, 4, 2, 5, 1, 3], 'A')
([0, 1, 4, 3, 2, 5], 'F') ([0, 4, 3, 1, 2, 5], 'A')
([0, 1, 4, 3, 5, 2], 'B') ([0, 4, 5, 3, 2, 1], 'A')
([0, 1, 4, 5, 2, 3], 'A') ([0, 5, 1, 2, 4, 3], 'A')
([0, 1, 4, 5, 3, 2], 'E') ([0, 5, 2, 1, 3, 4], 'A')
([0, 1, 5, 2, 3, 4], 'D') ([0, 5, 3, 1, 4, 2], 'A')
([0, 1, 5, 2, 4, 3], 'B') ([0, 5, 4, 2, 3, 1], 'A')
([0, 1, 5, 3, 2, 4], 'F') ([0, 1, 2, 3, 5, 4], 'B')
([0, 1, 5, 3, 4, 2], 'C') ([0, 1, 3, 4, 2, 5], 'B')
([0, 1, 5, 4, 2, 3], 'E') ([0, 1, 4, 3, 5, 2], 'B')
([0, 1, 5, 4, 3, 2], 'A') ([0, 1, 5, 2, 4, 3], 'B')
([0, 2, 1, 3, 4, 5], 'D') ([0, 2, 1, 5, 3, 4], 'B')
([0, 2, 1, 3, 5, 4], 'E') ([0, 2, 3, 4, 1, 5], 'B')
([0, 2, 1, 4, 3, 5], 'A') ([0, 2, 4, 5, 1, 3], 'B')
([0, 2, 1, 4, 5, 3], 'F') ([0, 2, 5, 4, 3, 1], 'B')
([0, 2, 1, 5, 3, 4], 'B') ([0, 3, 1, 5, 4, 2], 'B')
([0, 2, 1, 5, 4, 3], 'C') ([0, 3, 2, 1, 4, 5], 'B')
([0, 2, 3, 1, 4, 5], 'C') ([0, 3, 4, 5, 2, 1], 'B')
([0, 2, 3, 1, 5, 4], 'D') ([0, 3, 5, 1, 2, 4], 'B')
([0, 2, 3, 4, 1, 5], 'B') ([0, 4, 1, 2, 5, 3], 'B')
([0, 2, 3, 4, 5, 1], 'E') ([0, 4, 2, 1, 3, 5], 'B')
([0, 2, 3, 5, 1, 4], 'A') ([0, 4, 3, 2, 5, 1], 'B')
([0, 2, 3, 5, 4, 1], 'F') ([0, 4, 5, 3, 1, 2], 'B')
([0, 2, 4, 1, 3, 5], 'F') ([0, 5, 1, 4, 2, 3], 'B')
([0, 2, 4, 1, 5, 3], 'A') ([0, 5, 2, 3, 1, 4], 'B')
([0, 2, 4, 3, 1, 5], 'E') ([0, 5, 3, 2, 4, 1], 'B')
([0, 2, 4, 3, 5, 1], 'D') ([0, 5, 4, 1, 3, 2], 'B')
([0, 2, 4, 5, 1, 3], 'B') ([0, 1, 2, 4, 3, 5], 'C')
([0, 2, 4, 5, 3, 1], 'C') ([0, 1, 3, 5, 2, 4], 'C')
([0, 2, 5, 1, 3, 4], 'C') ([0, 1, 4, 2, 5, 3], 'C')
([0, 2, 5, 1, 4, 3], 'E') ([0, 1, 5, 3, 4, 2], 'C')
([0, 2, 5, 3, 1, 4], 'F') ([0, 2, 1, 5, 4, 3], 'C')
([0, 2, 5, 3, 4, 1], 'A') ([0, 2, 3, 1, 4, 5], 'C')
([0, 2, 5, 4, 1, 3], 'D') ([0, 2, 4, 5, 3, 1], 'C')
([0, 2, 5, 4, 3, 1], 'B') ([0, 2, 5, 1, 3, 4], 'C')
([0, 3, 1, 2, 4, 5], 'F') ([0, 3, 1, 2, 5, 4], 'C')
([0, 3, 1, 2, 5, 4], 'C') ([0, 3, 2, 4, 1, 5], 'C')
([0, 3, 1, 4, 2, 5], 'E') ([0, 3, 4, 5, 1, 2], 'C')
([0, 3, 1, 4, 5, 2], 'D') ([0, 3, 5, 4, 2, 1], 'C')
([0, 3, 1, 5, 2, 4], 'A') ([0, 4, 1, 3, 2, 5], 'C')
([0, 3, 1, 5, 4, 2], 'B') ([0, 4, 2, 3, 5, 1], 'C')
([0, 3, 2, 1, 4, 5], 'B') ([0, 4, 3, 1, 5, 2], 'C')
([0, 3, 2, 1, 5, 4], 'F') ([0, 4, 5, 2, 1, 3], 'C')
([0, 3, 2, 4, 1, 5], 'C') ([0, 5, 1, 4, 3, 2], 'C')
([0, 3, 2, 4, 5, 1], 'A') ([0, 5, 2, 3, 4, 1], 'C')
([0, 3, 2, 5, 1, 4], 'D') ([0, 5, 3, 2, 1, 4], 'C')
([0, 3, 2, 5, 4, 1], 'E') ([0, 5, 4, 1, 2, 3], 'C')
([0, 3, 4, 1, 2, 5], 'D') ([0, 1, 2, 4, 5, 3], 'D')
([0, 3, 4, 1, 5, 2], 'E') ([0, 1, 3, 5, 4, 2], 'D')
([0, 3, 4, 2, 1, 5], 'A') ([0, 1, 4, 2, 3, 5], 'D')
([0, 3, 4, 2, 5, 1], 'F') ([0, 1, 5, 2, 3, 4], 'D')
([0, 3, 4, 5, 1, 2], 'C') ([0, 2, 1, 3, 4, 5], 'D')
([0, 3, 4, 5, 2, 1], 'B') ([0, 2, 3, 1, 5, 4], 'D')
([0, 3, 5, 1, 2, 4], 'B') ([0, 2, 4, 3, 5, 1], 'D')
([0, 3, 5, 1, 4, 2], 'F') ([0, 2, 5, 4, 1, 3], 'D')
([0, 3, 5, 2, 1, 4], 'E') ([0, 3, 1, 4, 5, 2], 'D')
([0, 3, 5, 2, 4, 1], 'D') ([0, 3, 2, 5, 1, 4], 'D')
([0, 3, 5, 4, 1, 2], 'A') ([0, 3, 4, 1, 2, 5], 'D')
([0, 3, 5, 4, 2, 1], 'C') ([0, 3, 5, 2, 4, 1], 'D')
([0, 4, 1, 2, 3, 5], 'E') ([0, 4, 1, 5, 3, 2], 'D')
([0, 4, 1, 2, 5, 3], 'B') ([0, 4, 2, 5, 3, 1], 'D')
([0, 4, 1, 3, 2, 5], 'C') ([0, 4, 3, 2, 1, 5], 'D')
([0, 4, 1, 3, 5, 2], 'A') ([0, 4, 5, 1, 2, 3], 'D')
([0, 4, 1, 5, 2, 3], 'F') ([0, 5, 1, 3, 2, 4], 'D')
([0, 4, 1, 5, 3, 2], 'D') ([0, 5, 2, 1, 4, 3], 'D')
([0, 4, 2, 1, 3, 5], 'B') ([0, 5, 3, 4, 2, 1], 'D')
([0, 4, 2, 1, 5, 3], 'E') ([0, 5, 4, 3, 1, 2], 'D')
([0, 4, 2, 3, 1, 5], 'F') ([0, 1, 2, 5, 3, 4], 'E')
([0, 4, 2, 3, 5, 1], 'C') ([0, 1, 3, 2, 4, 5], 'E')
([0, 4, 2, 5, 1, 3], 'A') ([0, 1, 4, 5, 3, 2], 'E')
([0, 4, 2, 5, 3, 1], 'D') ([0, 1, 5, 4, 2, 3], 'E')
([0, 4, 3, 1, 2, 5], 'A') ([0, 2, 1, 3, 5, 4], 'E')
([0, 4, 3, 1, 5, 2], 'C') ([0, 2, 3, 4, 5, 1], 'E')
([0, 4, 3, 2, 1, 5], 'D') ([0, 2, 4, 3, 1, 5], 'E')
([0, 4, 3, 2, 5, 1], 'B') ([0, 2, 5, 1, 4, 3], 'E')
([0, 4, 3, 5, 1, 2], 'E') ([0, 3, 1, 4, 2, 5], 'E')
([0, 4, 3, 5, 2, 1], 'F') ([0, 3, 2, 5, 4, 1], 'E')
([0, 4, 5, 1, 2, 3], 'D') ([0, 3, 4, 1, 5, 2], 'E')
([0, 4, 5, 1, 3, 2], 'F') ([0, 3, 5, 2, 1, 4], 'E')
([0, 4, 5, 2, 1, 3], 'C') ([0, 4, 1, 2, 3, 5], 'E')
([0, 4, 5, 2, 3, 1], 'E') ([0, 4, 2, 1, 5, 3], 'E')
([0, 4, 5, 3, 1, 2], 'B') ([0, 4, 3, 5, 1, 2], 'E')
([0, 4, 5, 3, 2, 1], 'A') ([0, 4, 5, 2, 3, 1], 'E')
([0, 5, 1, 2, 3, 4], 'F') ([0, 5, 1, 3, 4, 2], 'E')
([0, 5, 1, 2, 4, 3], 'A') ([0, 5, 2, 4, 1, 3], 'E')
([0, 5, 1, 3, 2, 4], 'D') ([0, 5, 3, 1, 2, 4], 'E')
([0, 5, 1, 3, 4, 2], 'E') ([0, 5, 4, 3, 2, 1], 'E')
([0, 5, 1, 4, 2, 3], 'B') ([0, 1, 2, 5, 4, 3], 'F')
([0, 5, 1, 4, 3, 2], 'C') ([0, 1, 3, 4, 5, 2], 'F')
([0, 5, 2, 1, 3, 4], 'A') ([0, 1, 4, 3, 2, 5], 'F')
([0, 5, 2, 1, 4, 3], 'D') ([0, 1, 5, 3, 2, 4], 'F')
([0, 5, 2, 3, 1, 4], 'B') ([0, 2, 1, 4, 5, 3], 'F')
([0, 5, 2, 3, 4, 1], 'C') ([0, 2, 3, 5, 4, 1], 'F')
([0, 5, 2, 4, 1, 3], 'E') ([0, 2, 4, 1, 3, 5], 'F')
([0, 5, 2, 4, 3, 1], 'F') ([0, 2, 5, 3, 1, 4], 'F')
([0, 5, 3, 1, 2, 4], 'E') ([0, 3, 1, 2, 4, 5], 'F')
([0, 5, 3, 1, 4, 2], 'A') ([0, 3, 2, 1, 5, 4], 'F')
([0, 5, 3, 2, 1, 4], 'C') ([0, 3, 4, 2, 5, 1], 'F')
([0, 5, 3, 2, 4, 1], 'B') ([0, 3, 5, 1, 4, 2], 'F')
([0, 5, 3, 4, 1, 2], 'F') ([0, 4, 1, 5, 2, 3], 'F')
([0, 5, 3, 4, 2, 1], 'D') ([0, 4, 2, 3, 1, 5], 'F')
([0, 5, 4, 1, 2, 3], 'C') ([0, 4, 3, 5, 2, 1], 'F')
([0, 5, 4, 1, 3, 2], 'B') ([0, 4, 5, 1, 3, 2], 'F')
([0, 5, 4, 2, 1, 3], 'F') ([0, 5, 1, 2, 3, 4], 'F')
([0, 5, 4, 2, 3, 1], 'A') ([0, 5, 2, 4, 3, 1], 'F')
([0, 5, 4, 3, 1, 2], 'D') ([0, 5, 3, 4, 1, 2], 'F')
([0, 5, 4, 3, 2, 1], 'E') ([0, 5, 4, 2, 1, 3], 'F')