first the largest eigenvalue of a stochastic matrix is indeed $1$ but this is not a sufficient to prove that a matrix is stochastic (consider for instance add to zero. Take
$
M=\begin{bmatrix}1& 0 & 1\\0&1& 0\\0&0&1\end{bmatrix}
$ which has maximal eigenvalue 1 but isn't stochastic (see also e.g. Proof that the largest eigenvalue of a stochastic matrix is $1$)).
Now to show that $G$ is stochastic (assuming $A$ is stochastic), just apply the definitions:
$$
\begin{align*}
\sum_j G_{i,j} & = \sum_j (\alpha A_{i,j} + {(1-\alpha)\over n} ee^{T}_{i,j})\\
&= \alpha \sum_j A_{i,j} + {(1-\alpha)\over n} \sum_j ee^{T}_{i,j}\\
&= \alpha \times 1 + {(1-\alpha)\over n} \sum_j ee^{T}_{i,j} \\
&\text{(since $A$ is stochastic)}\\
&= \alpha + {(1-\alpha)\over n} \sum_j 1 \\
&= \alpha + (1-\alpha) = 1
\end{align*}
$$
Does this answer your question?