The $\Leftrightarrow$ symbol usually means Logical equivalence :
In logic, two statements $p$ and $q$ are logically equivalent if they have the same "logical content". That is, if they have the same truth value in every model.
But it can also mean Logical biconditional :
the logical connective of two statements asserting "$p \text { if and only if } q$".
The two are different but strongly related concepts :
Formulas $p$ and $q$ are logically equivalent if and only if the statement $p \text { iff } q$ is a tautology.
The link with logical proof is through the so-called Substitution Theorem of logical equivalents of classical propositional logic : if two formulas are logically equivalent then they are substitutable.
That is, if we have $A \Leftrightarrow B$, $C_A$ is a formula containing formula $A$ and $C_B$ is obtained replacing $A$ with $B$ in $C_A$, we have that if $C_A$ is provable also $C_B$ is.
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