Goal: explicitly find a nilpotent element of the group algebra $\Bbb C G$ for some finite group $G$. This exists if and only if $G$ is non abelian by Maschke's theorem and Wedderburn-Artin.
By Maschke's theorem, the group algebra $\Bbb C G$ is semisimple for finite $G$. So for any non-abelian group $G$, there is a nontrivial Wedderburn component, and thus nilpotent elements.
Take $G=D_{8}$, the dihedral group or order $8$. Then $G$ is non-abelian and we know that the irreducible representations have dimensions $1,1,1,1$, and $2$. Thus $$\Bbb C G\cong \Bbb C^{\oplus 4}\oplus M_2(\Bbb C)$$ and under this map we have nilpotent elements like $$\left(0,0,\begin{bmatrix}0 & 1 \\ 0 & 0\end{bmatrix} \right).$$
In theory, then, we should be able to find nilpotent elements in $\Bbb C G$. We know they exist, but we don't know the actual correspondence $\Bbb C G\tilde \to \Bbb C^{\oplus 4}\oplus M_2(\Bbb C)$.
My only lead: there is a well-known result we can use to calculate central primitive idempotents. For $D_8$, with the presentation
$$D_8=\langle a,b: a^4=b^2=abab=1\rangle,$$ the element corresponding to the $2\times 2$ identity matrix (i.e., the element $(0,0,\text{Id}_2)$), is $$\frac{1}{2}(1-a^2).$$
But this is not really helpful, and I still have no leads on how to get the element $\left(0,0,\begin{pmatrix}0,& 1\\ 0 & 0\end{pmatrix}\right)$ for example.
I have done all of the guess work I can. For the case $G=D_8$, a nilpotent must square to $0$, so I checked elements of the form $\sum_{G}^8c_ig$ for $c_i\in\{-3,-2,1,0,1,2,3\}$ with no luck. If there are no "easy" nilpotent elements, then I will need to get more clever with the search.
Note: there is nothing special about $D_8$. I just picked it because the two dimensional representation was easy to start playing with by hand in the first place.