Let me get you started. For $k=1,2,\dots,n$ let $p_k$ be the probability that the roller loses if he rolls $k,$ and that does not immediately win the game. Therefore, the probability that the first player loses is $${1\over n}\sum_{k=1}^np_k$$
It seems to me that the easiest way to compute $p_k$ will be in decreasing order, starting with $k=n$ and progressing down to $k=1$. When $k= n$ we have
$$p_n= {n-1\over n} + {1\over n}\left(1-p_n\right)\implies p_n={n\over n+1}$$
because, if the roller rolls $n$, he will lose if his opponent rolls anything but $n$, and in the case where the opponent does rolls $n$, he loses if the opponent doesn't lose.
Similarly, $$
\begin{align}
p_{n-1}&={n-2\over n} + {1\over n}\left(1-p_{n-1}\right) + {1\over n}\left(1-p_n\right)\\
p_{n-1}&=1-{1\over n}p_{n-1}-{1\over n}p_n\\
{n+1\over n}p_{n-1}&=1-{1\over n+1}\\
p_{n-1}&={n^2\over(n+1)^2}
\end{align}
$$
Can you continue?
EDIT
Now that a complete solution has been given, I will work out the details. I claim that with $p_k$ defined as above, we have
$$p_{n-j}=\left({n\over n+1}\right)^{n-j},\ j=0,1,\dots,n-1$$
The $j=0$ case has been done above. Assuming the theorem is true for $0,1,\dots,j-1,$, we have $$
\begin{align}
p_{n-j}&={n-j-1\over n}+{1\over n}\sum_{k=n-j}^n(1-p_k)\\
\left(1+\frac1n\right)p_{n-j}&=1-\frac1n\sum_{k=0}^{j-1}p_{n-k}\\
\left({n+1\over n}\right)p_{n-j}&=1-\frac1n\sum_{k=0}^{j-1}\left({n\over n+1}\right)^{k+1}\\
\left({n+1\over n}\right)p_{n-j}&=1-\frac1n\frac{\left({n\over n+1}\right)^{j+1}-{n\over n+1}}{{n\over n+1}-1}\\
\left({n+1\over n}\right)p_{n-j}&=1-\frac1n{n\over n+1}\frac{\left({n\over n+1}\right)^{j}-1}{{-1\over n+1}}=1-\left(1-\left(n\over n+1\right)^j\right)\\
p_{n-j}&=\left({n\over n+1}\right)^{j+1}
\end{align}
$$
Therefore, the probability that the first player loses is $$
\frac1n\sum_{j=0}^{n-1}\left({n\over n+1}\right)^{j+1}=
\frac1n\frac{\left({n\over n+1}\right)^{n+1}-{n\over n+1}}{{n\over n+1}-1}=\frac1n{n\over n+1}\frac{\left({n\over n+1}\right)^n-1}{{-1\over n+1}}=1-\left({n\over n+1}\right)^n$$
Note that this is precisely the complement of the probability that joriki computed in his solution. The problem lies in the description of the game in the question: "the game is over when a face shows up with point less than the previous toss and that person loses." It isn't at all clear who "that person" is, as the phrase has no antecedent. I interpreted it to mean that the first player who rolls a smaller number wins, and joriki interpreted it oppositely. Note that joiki says that the first player loses if the first non-monotonically increasing sequence has odd length, so that if the first $3$ rolls are $3,4,2$ the first player loses. In my interpretation, since it is the first player who rolled the $2,$ the first player wins. It's a bit surprising that nobody (including joriki and me) noticed that we were using different rules.
A similar approach will give the expected number of rolls, and this time, reassuringly, I get the same answer as joriki. If we let $e_k$ be the expected number number of rolls remaining, if the current point is $k$ then the expected number of rolls in the game is $$E=1+\frac1n\sum_{k=1}^ne_k$$ and in a manner exactly analogous to the calculations above, we find that $$e_{n-j}=\left(n\over n-1\right)^{j+1},\ j=0,1,\dots,n-1$$ and that $$E=\left({n\over n-1}\right)^n=\left(1-\frac1n\right)^{-n}$$