I noticed numerically that real parts of diagonal elements of $(I-U)^{-1}(I+U)$ are zero (assuming $I-U$ is invertible), where $I$ is identity matrix and $U$ is a unitary matrix ($U^\dagger U=I$).
A good example is provided by @copper.hat: take $U={1+i\over \sqrt{2}} I$, then $(I-U)^{-1} (I+U) = (1+\sqrt{2})i I$.
I have tried to use every answer in this question (Inverse of the sum of matrices) but none of them gives me any hints how to prove this.
By the way, here is a Mathematica script I used to check this using random unitary matrices (adapted here: https://mathematica.stackexchange.com/questions/11074/creating-a-random-normal-matrix):
n = 5; (*any dimension works here*)
q = Orthogonalize[
RandomVariate[NormalDistribution[], {n, n}] +
I RandomVariate[NormalDistribution[], {n, n}]];
Re[Diagonal[Inverse[IdentityMatrix[n] - q].(IdentityMatrix[n] + q)]]
I have to apologize for making too many mistakes at the beginning (even the title was wrong.). I hope some one can help me understand it.