Let $X$ be a random variable such that $E(X^2)<\infty$. Let $m$ denote a median of $X$ (that is to say any number $m$ such that $P(X\leq m)=P(X>m)=\frac 12$) and $\sigma$ its standard deviation. It's known that $|E(X)-m|\leq \sigma$ (see this for example).
Out of curiosity, I'm looking for an example of a distribution such that $E(X)-m = \sigma$ (that is to say it has maximal mean absolute deviation)
If $E(X)-m = \sigma$, it's not hard to prove (see my post for example) that we must have $$P(X-E(X)\leq -\sigma)=\frac12$$
The last equality is quite intuitive: in a discrete setting, if there's one outlier much larger than the rest of the values, $E(X)$ will be much higher than $m$, hence $X-E(X)$ will be mostly negative.
I can't come up with an example of such distribution off the top of my head.