The spherical centroid exists by the spherical version of Ceva's theorem.
Assuming that $A,B,C$ are three points on a unit sphere centered at $O$, we may join $A$ with the midpoint $M_A$ of the $BC$ side in the spherical triangle $ABC$. The plane through $A,M_A,O$ meets the $ABC$ plane at a line $\ell_A$, the plane through $B,M_B,O$ meets the $ABC$ plane at a line $\ell_B$. Assuming that $\ell_A$ and $\ell_B$ meet at $G$ in the $ABC$ plane, the spherical centroid of the spherical triangle $ABC$ is just the intersection between the $OG$ ray and the original sphere, i.e. $\frac{G}{\left\|G\right\|}$.
It follows that you just need to compute the (planar) centroid of the euclidean triangle $ABC$, since the $OM_A$ ray meets the $BC$ segment at its midpoint on so on.
Long story short, the answer is just given by $\color{red}{\frac{u+v+w}{\left\|u+v+w\right\|}}$, since the spherical medians are given by the central projections of the medians of the planar triangle $ABC$.