Let $V$ be a finite-dimensional vector space over $\mathbb{F}$. In what follows, I assume as known $\operatorname{Bilinear}(V^* \times V, \mathbb{F}) \cong V \otimes V^*$ (since the derivation of this canonical isomorphism is covered in Greub's Multilinear Algebra) and also that $V \cong V^{**}$. Thus what I want to show is:
Lemma: $\operatorname{Bilinear}(V^* \times V, \mathbb{F}) \cong \mathscr{L}(V,V)$.
Let $\varepsilon : V^* \times V \to \mathbb{F}$ be the bilinear map defined for all $f \in V^*, v \in V$ as: $$\varepsilon:(f,v) \mapsto f(v)\,. $$ Assume we are given a linear transformation $A \in \mathscr{L}(V,V)$, then this induces the bilinear map: $$\Phi_A \in \operatorname{Bilinear}(V^* \times V, \mathbb{F}), \quad \Phi_A: (f,v) \mapsto \varepsilon(f, Av)\,. $$ By the bilinearity of $\varepsilon$ and the fact that $\mathscr{L}(V,V)$ is a vector space, it is fairly clear that the assignment $\quad A \mapsto \Phi_A \quad$ is a linear map from $\mathscr{L}(V,V) \to \operatorname{Bilinear}(V^* \times V, \mathbb{F})$. Thus, in order to conclude the proof it suffices to show that the assignment is bijective.
Surjectivity: Let $\beta \in \operatorname{Bilinear}(V^* \times V, \mathbb{F})$ . Fix a basis $v^1, \dots, v^n$ of $V$.
Then for all $i$, we have that $\beta(\cdot,v^i) \in V^{**} \cong V$. By (bi)linearity, the behavior of $\beta$ is completely determined by the behavior of the $n$ functions $\beta(\cdot, v^1),\dots,\beta(\cdot, v^n)$.
Let $A \in \mathscr{L}(V,V)$ be such that for all $i$: $Av^i "=" \beta(\cdot, v^i)$ (this makes sense since the isomorphism $V \cong V^{**}$ is canonical). Then we have that $\beta = \Phi_A = \varepsilon(\cdot, A(\cdot))\,.$
Injectivity: Assume $\Phi_A=\Phi_{A'}$. Then $$0=\Phi_A-\Phi_{A'}=\varepsilon(\cdot,A(\cdot))-\varepsilon(\cdot,A'(\cdot))=\varepsilon(\cdot,(A-A')(\cdot))\,, $$ the last equality following from (bi)linearity.
For any $v\in V$, clearly, $\varepsilon(f, v)=f(v)=0$ for all $f \in V^*$ if and only if $v = 0$.
Since for any fixed $v$, $\varepsilon(f, (A-A')v)=0$ for all $f \in V^*$, it follows that $(A-A')v=0$ for any $v \in V$. Thus $A-A'=0$ and $A=A'$. $\square$
Is this correct?