edit: This answer is incorrect, but I'm leaving it in place temporarily in case it can be fixed.
While the other answers do provide orderings that cannot be transformed into each other by field automorphisms, one might also ask whether the orderings could be transformed into each other by any order isomorphism, field-preserving or not.
Now, any ordered field is a dense linear order without endpoints. A countable dense linear order without endpoints is isomorphic to $\mathbb Q$. So (at the time of writing) all the existing answers, being countable, are order-isomorphic. (Note in particular that the Archimedean property depends on the field structure as well as the order structure, so need not be preserved by general order isomorphisms.)
That's enough to satisfy the original question, but can we have two orders on the same field with different order types?
We can answer this question with a variation of the $\mathbb Q(\alpha)$ example. We can choose transcendental numbers $\alpha_i$ such that $\mathbb R = \mathbb Q(\alpha_i : i \in I)$, where $|I|$ is the transcendence degree of $\mathbb R$ over $\mathbb Q$.
We can then order $\mathbb Q(x_i : i \in I)$, polynomials over $\mathbb Q$ in $|I|$-many variables, by mapping $x_i$ to $\alpha_i$ for each $i$. The result will be order-isomorphic to $\mathbb R$, of course.
But we can also map $x_i$ to $\alpha_{f(i)}$, where $f : I \to I$ is some injective, non-surjective function. Then the result will be order-isomorphic to $\mathbb R$ with some "holes", with some transcendental numbers missing. Importantly, and unlike the countable case, the ordering can "detect" this removal, because $\mathbb R$-with-holes is not complete: there are sets bounded above but with no supremum. (In the countable case there were so many holes already that a couple of extra ones wouldn't make any difference.)
So, polynomials over $\mathbb Q$ with sufficiently many unknowns can actually be ordered in ways not only such that field automorphisms can't transform one ordering into the other, but the orderings actually have different order types altogether.