The following reformulation of properness is often very useful in practice.
Proposition. (Lee, Introduction to smooth manifolds, Proposition 21.5) Let $M$ be a manifold and $G$ a Lie group acting continuously on $M$. The following are equivalent.
- The action is proper.
- If $(p_i)$ is a sequence in $M$ and $(g_i)$ is a sequence in $G$ such that both $(p_i)$ and $(g_i\cdot p_i)$ converge, then a subsequence of $(g_i)$ converges.
Now, we can easily prove that your action is proper by proving that the second item in this proposition holds.
Let $(x_n,y_n,z_n)\in\Bbb R^3-\{0\}$ and $t_n\in\Bbb R^*$ be such that $(x_n,y_n,z_n)$ and $(t_nx_n,t_ny_n,t_nz_n)$ converge. Then,
$$\lim_{n\to\infty}(x_n,y_n,z_n)=(x,y,z)\in\Bbb R^3-\{0\}.$$
Since $(x,y,z)\in\Bbb R^3-\{0\}$, one of the coordinates is non-zero, and hence we may assume without loss of generality that $x\neq 0$. Hence $x_n\to x\neq 0$ as $n\to\infty$. In particular, $x_n\neq 0$ for all $n$ large enough, so
$$\lim_{n\to\infty}\frac{1}{x_n}=\frac{1}{x}.\tag{1}$$
(By removing enough of the first elements of the sequence.) Now, we are given that $(t_nx_n,t_ny_n,t_nz_n)$ also converges, so
$$\lim_{n\to\infty}t_nx_n=a,\tag{2}$$
for some $a\in\Bbb R$. Putting $(1)$ and $(2)$ together, we get
$$\lim_{n\to\infty}t_n=\lim_{n\to\infty}t_nx_n\frac{1}{x_n}=\left(\lim_{n\to\infty}t_nx_n\right)\left(\lim_{n\to\infty}\frac{1}{x_n}\right)=\frac{a}{x}\in\Bbb R.$$
The second equality is justified since both limit exist. So $t_n$ converges in $\Bbb R$. The last thing we need to check is that the limit is actually in $\Bbb R^*$. But this must be the case as otherwise
$$\lim_{n\to\infty}(t_nx_n,t_ny_n,t_nz_n)=(0\cdot x,0\cdot y,0\cdot z)=(0,0,0)\notin\Bbb R^3-\{0\}$$
(because $(x_n,y_n,z_n)$ converges to $(x,y,z)$). This shows that the action is proper and hence the quotient $(\Bbb R^3-\{0\})/\Bbb R^*$ is a manifold.
(The manifold that you constructed with this quotient is called a real projective space, and is usually denoted $\Bbb{RP}^3$.)