No, they are not isomorphic.
Pure Algebra tells us that the dimension of each is equal to the degree of the monic polynomial mentioned in its definition.
Let $\alpha$ be the real root of $X^3+X+1$, so that this polynomial factors as $(X-\alpha)(X^2+\alpha X+\alpha^2+1)$, where the second, quadratic, factor has negative discriminant. Call one its (complex) roots $\beta$. Then we map
\begin{align}
\Bbb R[X]&\>\longrightarrow\>\Bbb C\oplus\Bbb R\\
f(X)&\>\mapsto\>\bigl(f(\beta),\,f(\alpha)\bigr)\>.
\end{align}
You see that the only way a polynomial $f$ can go to zero is if $f(\beta)=f(\alpha)=0$, in other words if and only if $(X^3+X+1)\big|f(X)$, so that the kernel of our map is $(X^3+X+1)$. This shows that we’ve established an isomorphism between $\Bbb C\oplus\Bbb R$ and $\Bbb R[X]/(X^3+X+1)\,$.