$\pi$ is irrational and $\dfrac{10}\pi$ is irrational, but their product is rational. In other words, you are right that it's not easy to prove that the product of two irrational numbers is rational.
Proving $\pi$ is irrational is not so easy: https://en.wikipedia.org/wiki/Proof_that_%CF%80_is_irrational
However, if $\dfrac{10}\pi$ is rational, then $\dfrac{10}\pi$ is $\dfrac n m$ for some integers $n$ and $m$, so $\pi = \frac{10m} n$, a rational number. Thus if $\pi$ is irrational, then $\dfrac{10} \pi\vphantom{\dfrac{\displaystyle\sum}\sum}$ must also be irrational.
PS: It would appear that I answer the wrong question. The question was about the product of an irrational number and a rational number.
Say $x$ is irrational and $r$ is rational. Suppose $xr$ is rational. Then for some integers $a,b,c,d$ we have
$$
x r = x \frac a b = \frac c d.
$$
Consequently
$$
x = \frac {cb}{da},
$$
and thus $x$ is rational.