For any vector space $X$ over $\mathbb{F}=\mathbb{R}/\mathbb{C}$, its algebraic dual $X^\#$ is a proper subset of $\mathbb{F}^X$, the set of all functions from $X$ to $\mathbb{F}$. The product topology of $\mathbb{F}^X$ is the topology of pointwise convergence.
Lemma 1. $X^\#$ is a closed subset of $\mathbb{F}^X$ under the product topology. In addition, $(X^\#, \tau^\#)$, where $\tau^\#$ is the subspace topology, is a topological vector space. That is, both vector addition $+$ and scalar multiplication are $\tau^\#$-continuous.
Lemma 2. The continuous dual of $(X^\#, \tau^\#)$ is exactly the space of evaluation maps $X^{\#*}=\{\delta_x: x\in X \}$, where $\delta_x: f\mapsto f(x)$ is the evaluation of $f$ at point $x$.
Lemma 3. If $Y\subset X^\#$ is a subspace which separate points in $X$, meaning, for every nonzero $x\in X$, there is some $f\in Y$ s.t. $f(x)\neq 0$, then $Y$ is $\tau^\#$-dense in $(X^\#, \tau^\#)$.
Lemma 4. (Hahn-Banach) If $X$ is a Banach space, then its continuous dual $X^*$ separates points in $X$.
Lemma 5(i). For a topological space $(X, \tau_F)$, where $\tau_F$ is the initial topology of a family of functions $F:=\{f: X\to Y\}$, where $Y$ is some other topological space, let $X'\subset X$ be a dense subspace, and let $F':=\{f|_{X'}:X'\to Y\}$ be the restriction of family $F$ on $X'$. Then the initial topology on $X'$, induced by $F'$, is the same as the subspace topology $\tau_F|_{X'}$.
Lemma 5(ii). Any function $g: X'\to Y$ continuous on $X'$, under the subspace topology, admits a continuous extension $\tilde{g}$ on $X$.
From these lemmas, it follows
Proposition. For a Banach space $X$, the weak*-continuous dual of $X^*$ is exactly the the space of evaluation maps $\{\delta_x: x\in X \}$, where $\delta_x$ is defined by $f\mapsto f(x)$.
Proof. Suppose $f: X^*\to \mathbb{F}$ is a weak$^*$-continuous linear functional. Note the weak$^*$ topology of $X^*$ is the same as the subspace topology it inherits from $(X^\#, \tau^\#)$, and $X^*$ is $\tau^\#$-dense in $X^\#$. Hence $f$ admits a $\tau^\#$-continuous extension on $X^\#$. But every such linear functional is an evaluation map, and so $f$ must be an evaluation map. $\square$