I think your question was misunderstood a little bit, but also largely answered
by Yuval Filmus. Since you wrote that $F$ has characteristic 2, I think you wanted to work in $\mathbb{Z} / 2\mathbb{Z}$.
Hence, I think you could better rephrase your question as:
Given the matrix A(as you defined it), prove that $det(A) \pmod{2}$ is equal to the number of derangements of $2n$ elements. This is in fact true.
The determinant is defined as $$\operatorname{det}(A)=\sum_{\sigma\in S_n}(\operatorname{sgn}{\sigma})\prod_{i=1}^n a_{i,\sigma(i)}$$
where $\operatorname{sgn}{\sigma}$ is the signature of the permutation $\sigma$. The nice thing about evaluating $\pmod{2}$ is that since $1 = -1 \pmod{2}$, all signatures are just 1, and hence $$\operatorname{det}(A) \pmod{2}= \operatorname{perm}(A)=\sum_{\sigma\in S_n}\prod_{i=1}^n a_{i,\sigma(i)} $$.
Where $\operatorname{perm}(A)$ is the permanent of $A$. It is the determinant except without the signatures.
Clearly, if $i = \sigma(i)$ for any $i$, then $a_{i,\sigma(i)} = 0$ and the permutation will be ignored by the determinant modulo 2. The only cases in which the permutation will not be ignored and $\prod_{i=1}^n a_{i,\sigma(i)}$ will evaluate to 1, are where $i \ne \sigma(i)$ for all $i$, or equivalently if $\sigma$ is a derangement. We are done.